Version 3.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Not a hazardous substance or mixture according to regulation (EC) No. 1272/2008.
2.2 Label Elements
This product has no labeling elements associated with EC directives or respective national laws.
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Chemical Names/Description
1,2,3-propanetriol; glycerin; glycol alcohol
Chemical Formula
C3H8O3
Component List
| Component | % Comp. | CAS # | EC # |
|---|---|---|---|
| Glycerol | 99 | 56-81-5 | 200-289-5 |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes
Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
Inhalation symptoms unlikely.
Ingestion
Nausea, headache, diarrhea.
Skin
Irritation.
Eyes
Irritation.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use media appropriate to the primary cause of fire.
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
Toxic gases and vapors may be released if involved in a fire. Glycerol decomposes aupon heating above 290C, forming corrosive gas (acrolein).
Hazardous Decomposition Products
Toxic gases and vapors may be released if involved in a fire. Glycerol decomposes aupon heating above 290C, forming corrosive gas (acrolein).
Hazardous Polymerization
Will not occur
5.3 Advice for Firefighters
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Contain spills with absorbing material such as sawdust. Sweep and place in covered disposal container. Wash area with water.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling.
7.2 Conditions for Safe Storage (including any incompatibles)
Keep in a tightly closed container, stored in a cooled, dry, ventilated area. Protect from physical damage. Isolate from incompatible materials (section 10).
Incompatibles
Strong oxidizers. Can react violently with acetic anhydride, calcium oxychloride, chromium oxides and alkali metal hydrides.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
ACGIH Threshold Limit Value (TLV):
10 mg/m3
OSHA Permissible Exposure Limit (PEL):
None established
8.2 Exposure Controls
Engineering Controls
Not expected to require any special ventilation.
Respiratory Protection
Not expected to require personal respirator usage.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear protective gloves and clean body covering clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | Clear oily liquid | b. Odor | None |
| c. Odor Threshold | N.A. | d. pH | neutral |
| e. Melting/Freezing Point (oC) | 18 | f. Boiling point (oC) | 290 |
| g. Flash Point (oC) | 199 (PM) | h. Evaporation Rate | No information found |
| i. Flammability | N.A. | j. Upper/Lower Flammability or Explosive Limits | NA |
| k. Vapor Pressure | 0.0025 @ 50C | l. Vapor Density (Air = 1) | 3.17 |
| m. Relative Density | 1.26 @ 20C | n. Water Solubility | Miscible |
| o. Partition Coefficient n-octanol/water | Log Pow -1.75 | p. Autoignition Temperature (oC) | 370 |
| q. Decomposition Temperature (oC) | No data | r. Viscosity | No data available. |
| s. Explosive Properties | N.A. | t. Oxidizing Properties | Not an oxidizer |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
Reactive with strong oxidizers- may ignite on contact.
10.2 Chemical Stability
Stable under recommended conditions of use and storage.
10.3 Possibility of Hazardous Reactions
Will not occur
10.4 Conditions to Avoid
Heat, flames, ignition sources, and incompatibles.
10.5 Incompatible Materials
Strong oxidizers. Can react violently with acetic anhydride, calcium oxychloride, chromium oxides and alkali metal hydrides.
10.6 Hazardous Decomposition Products
Toxic gases and vapors may be released if involved in a fire. Glycerol decomposes aupon heating above 290C, forming corrosive gas (acrolein).
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
12727
Dermal Rabbit LD50 (mg/kg)
0
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| Glycerol | No | No | None |
Potential Health Effects
Inhalation
Due to the low vapor pressure, inhalation of the vapors at room temperatures in unlikely. Inhalation of mist may cause irritation of respiratory tract.
Ingestion
Low toxicity. May cause nausea, headache, diarrhea.
Skin
May cause irritation.
Eyes
May cause irritation.
Carcinogenicity
According to definitions of the U.S. Hazard Communication Standard and the Canadian WHMIS Regulation, this material is not listed on the NTP, IARC, ACGIH, or OSHA carcinogen lists, and there are no studies implicating components as cancer causing agents in humans or animals.
Mutagenicity
No information found.
Reproductive Toxicity
No information found.
Teratogenic Effects
No information found.
Routes of Entry
No information found.
Target Organ Statement
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of this substance.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | No data | No data | EC3 : >10,000 mg/L | EC50 (16hrs) > 10000 mg/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
12.2 Persistence and Degradability
Readily biodegradable
12.3 Bioaccumulative Potential
No data
12.4 Mobility in Soil
No data
12.5 Results of PBT and vPvB Assessment
Not PBT or vPvB
12.6 Other Adverse Effects
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | N.A. | N.A. | N.A. | N.A. |
| 14.2 Shipping Name | Not Regulated | Not Regulated | Not Regulated | Not Regulated |
| 14.3 Hazard Class | N.A. | N.A. | N.A. | N.A. |
| 14.4 Packing Group | N.A. | N.A. | N.A. | N.A. |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| Glycerol | No | No | No | Yes | Yes |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
5/29/2015 - Updated Sections 2.1 and 3.1
4/16/2013 - Released Version 1.0
NFPA Codes
Health 0 Flammability 1 Reactivity 0
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.