Version 3.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]
H360 - Toxic to Reproduction (Category 1B)
2.2 Label Elements
| GHS Label Elements | ||
 | DANGER H360 - May damage fertility or the unborn child. | |
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.1 Substance
Chemical Names/Description
ortho-Boric acid, boracic acid, Borofax (H3BO3)
Chemical Formula
H3BO3
Component List
| Component | % Comp. | CAS # | EC # |
|---|---|---|---|
| Boric Acid | 100 | 10043-35-3 | 233-139-2 |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes
Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
May be absorbed from the mucous membranes of the respiratory tract, and depending on the amount of exposure could result in symptoms paralleling ingestion.
Ingestion
Depending on the amount of exposure, ingestion could result in the development of nausea, vomiting, diarrhea, drowsiness, rash, headache, fall in body temperature, low blood pressure, renal injury, cyanosis, coma, and death. Adult fatal dose reported at 5 to > 30 grams.
Skin
Symptoms of skin absorption parallel inhalation and ingestion.
Eyes
Redness, itching and pain.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use media appropriate to the primary cause of fire.
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
N.A.
Hazardous Decomposition Products
Loses chemically combined water upon heating, forming metaboric acid (HBO2) at 212-221 F, then pyroboric acid (H2B4O7) at 285 - 320 F, and Boric anhydride at higher temperature.
Hazardous Polymerization
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
5.3 Advice for Firefighters
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Ventilate area of leak or spill. Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling.
7.2 Conditions for Safe Storage (including any incompatibles)
Keep in a tightly closed container, stored in a cooled, dry, ventilated area.
Incompatibles
Potassium, acetic anhydride, alkalis, carbonates, and hydroxides.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
ACGIH Threshold Limit Value (TLV):
10 mg/m3 total dust
OSHA Permissible Exposure Limit (PEL):
15 mg/m3 total dust
8.2 Exposure Controls
Engineering Controls
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Respiratory Protection
For conditions of use where exposure to the dust or mist is apparent, a full-face dust/mist respirator may be worn. For emergencies or instances where the exposure levels are not known, use a full-face positive-pressure, air-supplied respirator.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | White powder or granules | b. Odor | None |
| c. Odor Threshold | N.A. | d. pH | 5.1 in 0.1 M soln. |
| e. Melting/Freezing Point (oC) | 169 C | f. Boiling point (oC) | Decomposes |
| g. Flash Point (oC) | N.A. | h. Evaporation Rate | N.A. |
| i. Flammability | N.A. | j. Upper/Lower Flammability or Explosive Limits | N.A. |
| k. Vapor Pressure | 2.6 @ 20 C (68 F) | l. Vapor Density (Air = 1) | N.A. |
| m. Relative Density | 1.43 | n. Water Solubility | 1g/18mL in cold H2O |
| o. Partition Coefficient n-octanol/water | log Kow -1.09 | p. Autoignition Temperature (oC) | N.A. |
| q. Decomposition Temperature (oC) | N.A. | r. Viscosity | No data available. |
| s. Explosive Properties | N.A. | t. Oxidizing Properties | Not an Oxidizer |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
May release hydrogen gas on reaction with strong reductants.
10.2 Chemical Stability
Stable under ordinary conditions of use and storage. If moisture is present, boric acid can be corrosive to iron.
10.3 Possibility of Hazardous Reactions
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
10.4 Conditions to Avoid
No information found.
10.5 Incompatible Materials
Potassium, acetic anhydride, alkalis, carbonates, and hydroxides.
10.6 Hazardous Decomposition Products
Loses chemically combined water upon heating, forming metaboric acid (HBO2) at 212-221 F, then pyroboric acid (H2B4O7) at 285 - 320 F, and Boric anhydride at higher temperature.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
2660
Dermal Rabbit LD50 (mg/kg)
no information found
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| Boric Acid | No | No | None |
Potential Health Effects
Inhalation
Causes irritation to the mucous membranes of the respiratory tract.
Ingestion
Harmful or fatal if ingested in sufficient volume.
Skin
Causes irritation to the skin.
Eyes
Causes irritation to the eyes.
Carcinogenicity
Not listed as a carcinogen by NTP or IARC.
Mutagenicity
No information found.
Reproductive Toxicity
Studies of dogs and rats have shown that infertility and damage to testes can result from acute or chronic ingestion of boric acid. Evidence of toxic effects on the human reproductive system is inadequate.
Teratogenic Effects
No information found.
Routes of Entry
Ingestion and inhalation. Not significantly absorbed through the intact skin. Readily absorbed through damaged or burned skin.
Target Organ Statement
Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of this substance.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (Limanda limanda, 72hrs) 75mg/L | LC50 (48hr, Daphnia) 133mg/L | NOEC 50mg/L | EC50:(3hr) 175mg/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | NOEC (21day, mortality) 175mg/kg soil | No data | EC50 24-250mg/L |
12.2 Persistence and Degradability
No data
12.3 Bioaccumulative Potential
No data
12.4 Mobility in Soil
logKp 0.34L/kg
12.5 Results of PBT and vPvB Assessment
Does not apply (inorganic)
12.6 Other Adverse Effects
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | N.A. | N.A. | N.A. | N.A. |
| 14.2 Shipping Name | Not regulated. | Not regulated. | Not regulated. | Not regulated. |
| 14.3 Hazard Class | N.A. | N.A. | N.A. | N.A. |
| 14.4 Packing Group | N.A. | N.A. | N.A. | N.A. |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| Boric Acid | No | No | No | Yes | Yes |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
5/29/2015 - Updated Sections 2.1 and 3.1
8/9/2013 - Released Version 1.0
NFPA Codes
Health 1 Flammability 0 Reactivity 0
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.