Version 3.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]
H314 - Skin Corrosion/Irritation (Category 1B)
2.2 Label Elements
| GHS Label Elements | ||
 | DANGER H314 - Causes severe skin burns and eye damage. | |
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixture
Chemical Names/Description
Buffered organic acid.
Component List
| Component | % Comp. | CAS # | EC # | 1278/2008 Classification |
|---|---|---|---|---|
| Formic Acid | 10 - 15 | 64-18-6 | 200-578-1 | H314 |
| Nonhazardous Proprietary Components | 85 - 90 | N.A. |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion
Do not induce vomiting. If swallowed and the person is conscious, immediately give large amounts of water. Get medical attention.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes
Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
Formic Acid:
Sore throat. Cough. Burning sensation. Shortness of breath. Laboured breathing. Unconsciousness. Symptoms may be delayed.
Nonhazardous Proprietary Components:
No information found.
Ingestion
Formic Acid:
Abdominal pain, nausea, diarrhea and vomiting can occur, leading to shortness of breath and death.
Nonhazardous Proprietary Components:
No information found.
Skin
Formic Acid:
Symptoms of redness, pain, and severe burn can occur.
Nonhazardous Proprietary Components:
No information found.
Eyes
Formic Acid:
Pain, Redness. Severe deep burns. Blurred vision.
Nonhazardous Proprietary Components:
No information found.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Use media appropriate to the primary cause of fire.
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
5.3 Advice for Firefighters
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Collect leaking liquid in sealable containers. Cautiously neutralized spilled liquid with weak alkaline solution. Then wash away with plenty of water.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling.
7.2 Conditions for Safe Storage (including any incompatibles)
Keep in a tightly closed container, stored in a cooled, dry, ventilated area.
Incompatibles
Formic Acid:
Sulfuric acid, strong caustics, furfuryl alcohol, hydrogen peroxide, strong oxidizers and bases. Reacts explosively with oxidizing agents.
Nonhazardous Proprietary Components:
Strong reducing agents, acid chlorides, phosphorus trichloride, phosphorus pentachloride, phosphorus oxychloride.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
Component: Formic Acid
ACGIH Threshold Limit Value (TLV):
5 ppm (TWA)
OSHA Permissable Exposure Limit (PEL):
5 ppm
Component: Nonhazardous Proprietary Components
ACGIH Threshold Limit Value (TLV):
GRAS
OSHA Permissable Exposure Limit (PEL):
None established
8.2 Exposure Controls
Engineering Controls
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Respiratory Protection
If the exposure limit is exceeded, wear a supplied air, full-facepiece respirator, airlined hood, or full-facepiece self-contained breathing apparatus.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | Clear, colorless liquid | b. Odor | None |
| c. Odor Threshold | N.A. | d. pH | Acidic |
| e. Melting/Freezing Point (oC) | 0 | f. Boiling point (oC) | 105 |
| g. Flash Point (oC) | N.A. | h. Evaporation Rate | 1.0 |
| i. Flammability | N.A. | j. Upper/Lower Flammability or Explosive Limits | N.A. |
| k. Vapor Pressure | N.A. | l. Vapor Density (Air = 1) | N.A. |
| m. Relative Density | 1.05 | n. Water Solubility | Soluble |
| o. Partition Coefficient n-octanol/water | Mixture | p. Autoignition Temperature (oC) | N.A. |
| q. Decomposition Temperature (oC) | Not applicable. | r. Viscosity | No data available. |
| s. Explosive Properties | N.A. | t. Oxidizing Properties | N.A. |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
Acidic solution. Reacts strongly with alkali. Will corrode metals.
10.2 Chemical Stability
Stable under ordinary conditions of use and storage.
10.3 Possibility of Hazardous Reactions
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
10.4 Conditions to Avoid
Incompatibles.
10.5 Incompatible Materials
Formic Acid:
Sulfuric acid, strong caustics, furfuryl alcohol, hydrogen peroxide, strong oxidizers and bases. Reacts explosively with oxidizing agents.
Nonhazardous Proprietary Components:
Strong reducing agents, acid chlorides, phosphorus trichloride, phosphorus pentachloride, phosphorus oxychloride.
10.6 Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
11000
Dermal Rabbit LD50 (mg/kg)
No Data
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| Formic Acid | No | No | None |
| Nonhazardous Proprietary Components | No | No | None |
Potential Health Effects
Inhalation
Formic Acid
Inhalation of vapors can cause severe irritation of nose, throat, and upper respiratory tract. Inhalation of higher concentrations may cause central nervous system effects and lung damage.
Nonhazardous Proprietary Components
No information found.
Ingestion
Formic Acid
Causes serious burns and corrosion of the mouth, throat, and esophagus, with immediate pain and difficult swallowing. Severe poisonings may cause shock, kidney damage.
Nonhazardous Proprietary Components
No information found.
Skin
Formic Acid
Corrosive. Severely irritating to the skin.
Nonhazardous Proprietary Components
No information found.
Eyes
Formic Acid
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage.
Nonhazardous Proprietary Components
No information found.
Carcinogenicity
Formic Acid
Not listed as a carcinogen by NTP or IARC.
Nonhazardous Proprietary Components
No information found.
Mutagenicity
Formic Acid
No information found.
Nonhazardous Proprietary Components
No information found.
Reproductive Toxicity
Formic Acid
No information found.
Nonhazardous Proprietary Components
No information found.
Teratogenic Effects
Formic Acid
No information found.
Nonhazardous Proprietary Components
No information found.
Routes of Entry
Formic Acid
Inhalation, ingestion, skin contact.
Nonhazardous Proprietary Components
No information found.
Target Organ Statement
Formic Acid
No information found.
Nonhazardous Proprietary Components
No information found.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
COMPONENT: Formic Acid
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (96 hr, zebrafish) 130mg/l | EC50 (48hr, daphnia) 450mg/l | EC50>1000mg/l | NOEC 72mg/l |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | LD50(redwing blackbird) 111mg/kg | No data | No data | No data |
COMPONENT: Nonhazardous Proprietary Components
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
12.2 Persistence and Degradability
Formic Acid
Readily biodegradable, 100% elimination in 14 days
Nonhazardous Proprietary Components
No data
12.3 Bioaccumulative Potential
Formic Acid
No data
Nonhazardous Proprietary Components
No data
12.4 Mobility in Soil
Formic Acid
log Koc 1.49
Nonhazardous Proprietary Components
No data
12.5 Results of PBT and vPvB Assessment
Formic Acid
not PBT / vPvB
Nonhazardous Proprietary Components
No data
12.6 Other Adverse Effects
Formic Acid
None
Nonhazardous Proprietary Components
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | 3265 | N.A. | 3265 | 3265 |
| 14.2 Shipping Name | Corrosive Liquid, Acidic, Organic, N.O.S. ( formic acid ) | Forbidden ( due to packaging performance testing - | Corrosive Liquid, Acidic, Organic, N.O.S. ( formic acid ) | Corrosive Liquid, Acidic, Organic, N.O.S. ( formic acid ) |
| 14.3 Hazard Class | 8 | N.A. | 8 | 8 |
| 14.4 Packing Group | II | N.A. | II | II |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| Formic Acid | Yes | No | No | Yes | Yes |
| Nonhazardous Proprietary Components | No | No | No | No | No |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
6/30/2015 - Released Version 1.0
NFPA Codes
Health 3 Flammability 0 Reactivity 0
Dangers
Formic Acid
H314 - Causes severe skin burns and eye damage.
Nonhazardous Proprietary Components
None
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.