Version 3.0
Date revised: 4/26/2019
SAFETY DATA SHEET
Conforms to regulation (EC) no. EU 453/2010
SECTION 1 - IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
1.1 Product Identifier
1.2 Relevant Identified Uses of the Substance/Mixture and Uses Advised Against
Investigational research by professional users
1.3 Details of the Supplier of the Safety Data Sheet
| Manufacturer National Diagnostics 305 Patton Drive Atlanta, GA 30036 (404) 699-2121 (800) 526-3867 info@nationaldiagnostics.com |
1.4 Emergency Telephone Number
ChemTel Inc.
Contract number MIS8894340
1-800 255-3924 (United States, Canada, Puerto Rico & US Virgin Islands)
01-800-099-0731 (Mexico)
400-120-0751 (China)
000-800-100-4086 (India)
1-300-954-583 (Australia)
0-800-591-6042 (Brazil)
+1-813-255-3924 (All other regions)
SECTION 2 - HAZARDS IDENTIFICATION
2.1 Classification of the Substance or Mixture
Classification according to Regulation (EC) No. 1272/2008 [EU-GHS/CLP]
H227 - Flammable Liquids (Category 4)
H319 - Serious Eye Damage/Eye Irritation (Category 2A)
2.2 Label Elements
| GHS Label Elements | ||
 | WARNING H227 - Combustible liquid. | |
2.3 Other Hazards
None found.
SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS
3.2 Mixture
Chemical Names/Description
Mixture of d-limonene, ethanol, isopropanol and water.
Component List
| Component | % Comp. | CAS # | EC # | 1278/2008 Classification |
|---|---|---|---|---|
| Ethanol | 15 - 20 | 64-17-5 | 200-578-6 | H225, H319 |
| Isopropyl Alcohol | 2 - 4 | 67-63-0 | 200-661-7 | H225, H319, H336 |
SECTION 4 - FIRST AID MEASURES
4.1 Description of First Aid Measures
Inhalation
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Ingestion
Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Call a physician.
Skin
Immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Eyes
Immediately flush eyes with plenty of water for at least fifteen minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
4.2 Most Important Symptoms and Effects, Both Acute and Delayed
Inhalation
Ethanol:
Cough, drowsiness, headache and fatigue.
Isopropyl Alcohol:
No information available.
Ingestion
Ethanol:
Burning sensation, confusion. dizziness, headacheand unconsciousness.
Isopropyl Alcohol:
No information available.
Skin
Ethanol:
Dryness.
Isopropyl Alcohol:
No information available.
Eyes
Ethanol:
Redness, pain and burning.
Isopropyl Alcohol:
No information available.
4.3 Indication of Any Immediate Medical Attention and Special Treatment Needed
Unknown/not applicable
SECTION 5 - FIRE FIGHTING MEASURES
5.1 Extinguishing media
Dry powder, foam, carbon dioxide. (Water may be ineffective.)
5.2 Special Hazards Arising from the Substance/Mixture
Hazardous Combustion Products
Thermal decomposition products may include carbon monoxide, carbon dioxide, and hydrocarbons.
Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
Hazardous Polymerization
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
5.3 Advice for Firefighters
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode.
5.4 Further Information
No data available.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
6.1 Personal Precautions
Wear appropriate protective equipment as specified in Section 8.
6.2 Environmental Precautions
Prevent discharge into the environment. Dike spills and stop leakage where practical. Do not allow material to enter drains.
6.3 Methods and Materials for Containment and Cleaning Up
Contain and clean up spill immediately, prevent from entering floor drains. Contain liquids using absorbents. Shovel all spill materials into disposal drum. Scrub spill area with detergent, flush with copious amounts of water.
6.4 References to Other Sections
For disposal information see Section 13. For protective clothing and equipment see Section 8.
SECTION 7 - HANDLING AND STORAGE
7.1 Precautions for Safe Handling
Avoid contact and inhalation. Do not get in eyes, on skin, on clothing. Wash thoroughly after handling.
7.2 Conditions for Safe Storage (including any incompatibles)
Keep in a tightly closed container, stored in a cooled, dry, ventilated area away from sources of heat or ignition. Protect from physical damage. Isolate from incompatible materials (section 10).
Incompatibles
Ethanol:
Strong oxidants, silver salts, acid chlorides, alkali metals, hydrazine, and many other substances.
Isopropyl Alcohol:
Strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, hydrogen-palladium combination, hydrogen peroxide-sulfuric acid combination, potassium tert-butoxide, hypochlorous acid, isocyanates, nitroform, phosgene, aluminum, oleum and perchloric acid.
7.3 Specific End Uses
Investigational research by professional users
SECTION 8 - EXPOSURE CONTROLS/PERSONAL PRECAUTIONS
8.1 Control Parameters
Component: Ethanol
ACGIH Threshold Limit Value (TLV):
1000 ppm
OSHA Permissable Exposure Limit (PEL):
None established
Component: Isopropyl Alcohol
ACGIH Threshold Limit Value (TLV):
400 ppm
OSHA Permissable Exposure Limit (PEL):
None established
8.2 Exposure Controls
Engineering Controls
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source.
Respiratory Protection
If exposure limits are exceeded, wear a full-face respirator with organic vapor cartridge and high efficiency dust mist filter. Beyond fifty times exposure limits or when exposure levels are not known, wear a full-face piece positive pressure respirator.
Eye Protection
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
Skin Protection
Wear protective gloves and clean body covering clothing.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on Basic Physical & Chemical Properties
| a. Appearance | Colorless, mobile liquid | b. Odor | Slight citrus odor |
| c. Odor Threshold | N.A. | d. pH | N.A. |
| e. Melting/Freezing Point (oC) | 0 | f. Boiling point (oC) | 82.2 |
| g. Flash Point (oC) | 61.1 | h. Evaporation Rate | 2.0 (Bu Acetate = 1) |
| i. Flammability | N.A. | j. Upper/Lower Flammability or Explosive Limits | N.A. |
| k. Vapor Pressure | 58 mm Hg @ 38C | l. Vapor Density (Air = 1) | 1.5 (air = 1) |
| m. Relative Density | 0.94 | n. Water Solubility | Soluble |
| o. Partition Coefficient n-octanol/water | Mixture | p. Autoignition Temperature (oC) | N.A. |
| q. Decomposition Temperature (oC) | Not applicable. | r. Viscosity | No data available. |
| s. Explosive Properties | N.A. | t. Oxidizing Properties | Not an oxidizer |
SECTION 10 - STABILITY AND REACTIVITY
10.1 Reactivity
Reacts with strong oxidizers.
10.2 Chemical Stability
Stable under normal conditions of use and storage.
10.3 Possibility of Hazardous Reactions
Will not occur under normal conditions of use (See Sections 10.4 & 10.5).
10.4 Conditions to Avoid
Heat, flame, incompatibles.
10.5 Incompatible Materials
Ethanol:
Strong oxidants, silver salts, acid chlorides, alkali metals, hydrazine, and many other substances.
Isopropyl Alcohol:
Strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, hydrogen-palladium combination, hydrogen peroxide-sulfuric acid combination, potassium tert-butoxide, hypochlorous acid, isocyanates, nitroform, phosgene, aluminum, oleum and perchloric acid.
10.6 Hazardous Decomposition Products
Carbon dioxide and carbon monoxide may form when heated to decomposition.
SECTION 11 - TOXICOLOGICAL INFORMATION
Product LD50 Values
Oral Rat LD50 (mg/kg)
39222
Dermal Rabbit LD50 (mg/kg)
No Data
Component Cancer List Status
| NTP Carcinogen | |||
| Known | Anticipated | IARC Category | |
|---|---|---|---|
| Ethanol | No | No | None |
| Isopropyl Alcohol | No | No | 3 |
Potential Health Effects
Inhalation
Ethanol
Can cause irritation to the lungs and upper respiratory tract. May cause headache or fatigue.
Isopropyl Alcohol
No information available.
Ingestion
Ethanol
May cause irritation or central nervous system effects if swallowed.
Isopropyl Alcohol
No information available.
Skin
Ethanol
May cause drying or irritation to the skin.
Isopropyl Alcohol
No information available.
Eyes
Ethanol
May cause irritation to the eyes.
Isopropyl Alcohol
No information available.
Carcinogenicity
Ethanol
Not listed as a known or possible carcinogen by NTP or IARC.
Isopropyl Alcohol
No information available.
Mutagenicity
Ethanol
No information available.
Isopropyl Alcohol
No information available.
Reproductive Toxicity
Ethanol
Consumption during pregnancy may adversely affect the unborn child.
Isopropyl Alcohol
No information available.
Teratogenic Effects
Ethanol
No information available.
Isopropyl Alcohol
No information available.
Routes of Entry
Ethanol
Inhalation, ingestion, skin contact.
Isopropyl Alcohol
No information available.
Target Organ Statement
Ethanol
Persons with pre-existing skin disorders or eye problems or impaired liver or kidney function may be more susceptible to the effects of the substance.
Isopropyl Alcohol
No information available.
SECTION 12 - ECOLOGICAL INFOMATION
12.1 Toxicity
COMPONENT: Ethanol
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (96 hour, fathead minnow) 14g/L | EC50 (48hr, daphnia) 5g/L | EC50 (72hrs) 275mg/L | IC50 >1g/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | EC50 155ppm vapor | No data |
COMPONENT: Isopropyl Alcohol
| Vertebrates | Invertebrates | Algae | Microorganisms | |
|---|---|---|---|---|
Aquatic Toxicity (ppm unless otherwise noted) | LC50 (96hrs, golden orfe) ~9g/L | No data | TT (7day) 1.8g/L | TT (16hr) 1g/L |
| Birds | Arthropods | Plants | Microorganisms | |
|---|---|---|---|---|
Terrestrial Environment Toxicity (ppm unless otherwise noted) | No data | No data | No data | No data |
12.2 Persistence and Degradability
Ethanol
Readily biodegradable (95% degradation in 15 days)
Isopropyl Alcohol
Readily biodegradable (>50% in 5 days)
12.3 Bioaccumulative Potential
Ethanol
No data
Isopropyl Alcohol
No data
12.4 Mobility in Soil
Ethanol
No data
Isopropyl Alcohol
No data
12.5 Results of PBT and vPvB Assessment
Ethanol
Not PBT or vPvB
Isopropyl Alcohol
not PBT / vPvB
12.6 Other Adverse Effects
Ethanol
None
Isopropyl Alcohol
None
SECTION 13 - DISPOSAL CONSIDERATIONS
13.1 Waste Treatment Methods
Offer surplus or non-recyclable product to licensed disposal company. Disposal is subject to user compliance with applicable law and product characteristics at time of disposal. Dispose of packaging as product.
SECTION 14 - TRANSPORT INFORMATION
| ADR/RID | IATA | IMO | DOT | |
|---|---|---|---|---|
| 14.1 UN Number | N.A. | N.A. | N.A. | N.A. |
| 14.2 Shipping Name | Not regulated. | Not regulated. | Not regulated. | Not regulated. |
| 14.3 Hazard Class | N.A. | N.A. | N.A. | N.A. |
| 14.4 Packing Group | N.A. | N.A. | N.A. | N.A. |
| 14.5 Environmental Hazards | N.A. | N.A. | Not regulated | N.A. |
| 14.6 Special Precautions | N.A. | N.A. | N.A. | N.A. |
SECTION 15 - REGULATORY INFORMATION
15.1 Safety, Health and Environmental Regulations/Legislation Specific for the Substance/Mixture
United States
TSCA Regulatory Statement
All intentional ingredients are listed on the TSCA Inventory.
SARA 311/312 Hazard Categories
| Component | Fire | Pressure | Reactivity | Acute | Chronic |
|---|---|---|---|---|---|
| Ethanol | Yes | No | No | Yes | Yes |
| Isopropyl Alcohol | Yes | No | No | Yes | Yes |
Europe
EEC Regulatory
All intentional ingredients are listed on the European EINECS Inventory.
SECTION 16 - OTHER INFORMATION
Revisional Updates
4/26/2019 - Updated Section 1.4
6/4/2015 - Released Version 1.0
NFPA Codes
Health 1 Flammability 2 Reactivity 0
Dangers
Ethanol
H225 - Highly flammable liquid and vapor.
H319 - Causes serious eye irritation.
Isopropyl Alcohol
H225 - Highly flammable liquid and vapor.
H319 - Causes serious eye irritation.
H336 - May cause drowsiness or dizziness.
MANUFACTURER DISCLAIMER: The information given herein is offered in good faith as accurate, but without guarantee. Conditions of the use and suitability of the product for particular uses are beyond our control. All risks of use of the product are therefore assumed by the user. Nothing is intended as a recommendation for uses which infringe valid patents or as extending license under valid patents. Appropriate warnings and safe handling procedures should be provided to handlers and users.